Srikrishna, A and Kumar, PP (1999) Spiroannulation of a cyclopentane ring. Synthesis of spiro[4.n](n+5)alk-2-en-1-ones. In: Journal of the Indian Chemical Society, 76 (11-12). pp. 521-526.
Full text not available from this repository. (Request a copy)
Official URL: http://www.indianchemicalsociety.org/
Abstract
A methodology based on Claisen rearrangement-Wacker oxidation and intramolecular aldol condensation strategy starting from cyclic ketones leading to spiro[4.n](n+5)alk-2-en-1-ones has been developed. Thus one-pot Claisen rearrangement of the alkyl alcohols 6a-c furnished the aldehydes 8a-c, which on regiospecific oxidation using Wacker conditions generated the keto-aldehydes 9a-c. Finally, intramolecular aldol condensation transformed the keto-aldehydes 9a-c into spiroannulated products 10a-c.
| Item Type: | Journal Article |
|---|---|
| Publication: | Journal of the Indian Chemical Society |
| Publisher: | Indian Chemical Society |
| Additional Information: | Copyright of this article belongs to Indian Chemical Society. |
| Department/Centre: | Division of Chemical Sciences > Organic Chemistry |
| Date Deposited: | 29 Jun 2011 08:39 |
| Last Modified: | 29 Jun 2011 08:39 |
| URI: | http://eprints.iisc.ac.in/id/eprint/38778 |
Actions (login required)
 |
View Item |
