Enantiodivergent total synthesis of microcarpalide from L-tartaric acid

Prasad, Kavirayani R and Penchalaiah, Kamala (2011) Enantiodivergent total synthesis of microcarpalide from L-tartaric acid. In: Tetrahedron, 67 (23). pp. 4268-4276.

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Abstract

Stereoselective approach for the synthesis of both enantiomers of bio-active decanolactone microcarpalide is described from L-tartaric acid. The synthesis of the key intermediates en route to the natural product is achieved from L-tartaric acid involving the elaboration of gamma-hydroxy amide derived from tartaric acid and ring opening of an epoxide derived from tartaric acid. (C) 2011 Elsevier Ltd. All rights reserved.

Item Type:	Journal Article
Publication:	Tetrahedron
Publisher:	Elsevier Science
Additional Information:	Copyright of this article belongs to Elsevier Science.
Keywords:	Decanolide;Microcarpalide;Tartaric acid;Total synthesis
Department/Centre:	Division of Chemical Sciences > Organic Chemistry
Date Deposited:	29 Jun 2011 08:53
Last Modified:	21 Oct 2011 09:29
URI:	http://eprints.iisc.ac.in/id/eprint/38618

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