Synthesis based on cyclohexadienes .23. Total synthesis of 5-epi-pupukean-2-one

Kaliappan, Krishna and Rao, Subba GSR (1997) Synthesis based on cyclohexadienes .23. Total synthesis of 5-epi-pupukean-2-one. In: Perkin Transactions 1 (22). pp. 3387-3392.

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Abstract

A new strategy for the construction of the isotwistane skeleton is reported from easily available cyclohexadienes which involves stereoselective alkylation of a bicyclooctenone derivative and a decarboxylative 5-exo-trig radical cyclisation as the key steps in the total synthesis of 5-epi-pupukean-2-one.

Item Type:	Journal Article
Publication:	Perkin Transactions 1
Publisher:	Royal Society of Chemistry
Additional Information:	Copyright of this article belongs to Royal Society of Chemistry.
Department/Centre:	Division of Chemical Sciences > Organic Chemistry
Date Deposited:	23 Jun 2011 06:57
Last Modified:	23 Jun 2011 06:57
URI:	http://eprints.iisc.ac.in/id/eprint/38518

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