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Synthesis based on cyclohexadienes .21. Total synthesis of (+/-)-hinesol and (+/-)-10-epi-hinesol

Janaki, SN and Rao, GSRS (1997) Synthesis based on cyclohexadienes .21. Total synthesis of (+/-)-hinesol and (+/-)-10-epi-hinesol. In: Perkin Transactions 1 (3). pp. 195-200.

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An efficient strategy for the construction of the spiro[4,5]decane and eremane systems is described which involves an acid-catalysed rearrangement of an endo alcohol, followed by an oxidative cleavage resulting in the generation of a spiro-system, as the key step, This methodology is extended to the total synthesis of (+/-)-hinesol and (+/-)-10-epi-hinesol 2.

Item Type: Journal Article
Publication: Perkin Transactions 1
Publisher: Royal Society of Chemistry
Additional Information: Copyright of this article belongs to Royal Society of Chemistry.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 23 Jun 2011 07:17
Last Modified: 23 Jun 2011 07:17
URI: http://eprints.iisc.ac.in/id/eprint/38516

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