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Stereospecific solid-state NaBH4-promoted reduction of 1-methylpentacyclo[,6).0(3,10).0(5,9)]undecane-8,11-dione

Bott, SG and Marchand, AP and Xing, DX and Shukla, R and Obrey, SJ and Venkatesan, K and Moorthy, JN (1997) Stereospecific solid-state NaBH4-promoted reduction of 1-methylpentacyclo[,6).0(3,10).0(5,9)]undecane-8,11-dione. In: Journal of Chemical Crystallography, 27 (11). pp. 661-665.

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NaBH4 reduction of a cage dione proceeds in a stereospecific fashion to give the endo,endo-diol. This reactivity is related to the crystal structure.

Item Type: Journal Article
Publication: Journal of Chemical Crystallography
Publisher: Springer
Additional Information: Copyright of this article belongs to Springer.
Keywords: Crystal structure;pentacyclo['6.03'k~ solid-state reduction.
Department/Centre: Division of Mechanical Sciences > Chemical Engineering
Date Deposited: 24 Jun 2011 06:59
Last Modified: 11 Oct 2018 17:46
URI: http://eprints.iisc.ac.in/id/eprint/38483

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