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Stereocontrolled synthesis of (+/-)-alpha-pinguisene and (+/-)-pinguisenol

Srikrishna, Adusumilli and Vijaykumar, Dange (1997) Stereocontrolled synthesis of (+/-)-alpha-pinguisene and (+/-)-pinguisenol. In: Perkin Transactions 1 (22). pp. 3295-3296.

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Total synthesis of (+/-)-alpha-pinguisene 1 and (+/-)-pinguisenol 2, employing an orthoester Claisen rearrangement and an intramolecular diazo ketone cyclopropanation reaction for the stereospecific construction of vicinal quaternary carbon atoms, is described.

Item Type: Journal Article
Publication: Perkin Transactions 1
Publisher: Royal Society of Chemistry
Additional Information: Copyright of this article belongs to Royal Society of Chemistry.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 24 Jun 2011 07:03
Last Modified: 24 Jun 2011 07:03
URI: http://eprints.iisc.ac.in/id/eprint/38481

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