Ramalingam, SK and Soundararajan, S (1967) Dimethyl Sulphoxide Complexes of rare earth chlorides. In: Zeitschrift fur anorganische und allgemeine Chemie, 353 (3-4). pp. 216-222.
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Dimethyl sulphoxide complexes of seven rare earth chlorides of the general formula $MCl_{3 . n}$ DMSO where M La, Ce, Pr, Nd, Sm, or Gd; n = 4 and M = Y; n = 3 have been isolated and characterized. The infrared studies reveal coordination through oxygen. The conductance data in acetonitrile, dimethyl formamide and dimethyl sulphoxide suggest a coordination number of 8 for lanthanons and 7 for yttrium. A bridge-type structure involving chlorine is postulated.
| Item Type: | Journal Article |
|---|---|
| Publication: | Zeitschrift fur anorganische und allgemeine Chemie |
| Publisher: | Verlag GmbH & Co. KGaA, Weinheim. |
| Additional Information: | The copyright belongs to Verlag GmbH & Co. KGaA, Weinheim. |
| Department/Centre: | Division of Chemical Sciences > Inorganic & Physical Chemistry |
| Date Deposited: | 18 Oct 2005 |
| Last Modified: | 27 Aug 2008 11:30 |
| URI: | http://eprints.iisc.ac.in/id/eprint/3842 |
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