Varamban, Vana S and Jacob, KT (1997) Relation between integral and partial properties of ternary solutions along different composition trajectories. In: High Temperature Materials and Processes, 16 (4). pp. 227-242.
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The relations between partial and integral properties of ternary solutions along composition trajectories suggested by Kohler, Colinet and Jacob, and along an arbitrary path are derived. The chemical potentials of the components are related to the slope of integral free energy by expressions involving the binary compositions generated by the intersections of the composition trajectory with the sides of the ternary triangle. Only along the Kohler composition trajectory it is possible to derive the integral free energy from the variation of the chemical potential of a single component with composition or vice versa. Along all other paths the differential of the integral free energy is related to two chemical potentials. The Gibbs-Duhem integration proposed by Darken for the ternary system uses the Kohler isogram. The relative merits of different limits for integration are discussed.
| Item Type: | Journal Article |
|---|---|
| Publication: | High Temperature Materials and Processes |
| Publisher: | Freund Publishing House |
| Additional Information: | Copyright of this article belongs to Freund Publishing House. |
| Department/Centre: | Division of Chemical Sciences > Materials Research Centre Division of Mechanical Sciences > Materials Engineering (formerly Metallurgy) |
| Date Deposited: | 30 Jun 2011 13:22 |
| Last Modified: | 30 Jun 2011 13:22 |
| URI: | http://eprints.iisc.ac.in/id/eprint/38385 |
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