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Pyridinidm Hexafluorotitanate and its Derivatives

Singh, Ram Niwas and Padma, DK (1995) Pyridinidm Hexafluorotitanate and its Derivatives. In: Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 25 (4). 653-662 .

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Pyridinium hexafluorotitanate, (C5H5NH)(2)TiF6, has been prepared by the reaction of titanium metal with pyridinium poly(hydrogen fluoride), PPHF, at room temperature. Making use of (C5H5NH)(2)TiF6 as a precursor, ammonium and alkali metal hexafluorotitanates, M(2)TiF(6) (M = NH4, Na, K, Rb and Cs) have been synthesized by metathesis. These hexafluorotitanates have been characterized by chemical analyses, infrared and NMR (H-1 and F-19) spectroscopy and powder X-ray diffraction methods. Indexed powder X-ray diffraction data for Rb2TiF6 and Cs2TiF6 have been reported.

Item Type: Journal Article
Publication: Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry
Publisher: Taylor and Francis Group
Additional Information: Copyright of this article belongs to Taylor and Francis Group.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 02 Jun 2011 10:05
Last Modified: 02 Jun 2011 10:05
URI: http://eprints.iisc.ac.in/id/eprint/38158

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