Chandrasekhar, S and Venkatesan, V (1995) Intramolecular Reactivity - Keto Participation in the Hydrolysis of N-Methyl-N-(9-Oxobicyclo[3.3.1]Nonan-2-Alpha-YL) Morpholinium Iodide, and A Cannizzaro-Type Reaction of 3-(2-Oxocyclohexyl)Propanal. In: Journal of Chemical Research (5). pp. 170-171.
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Abstract
Mechanistic studies of two intramolecular processes, nucleophilic displacement of N-methylmorpholinium in N-methyl-N-{9-oxobicyclo[3,3,1]nonan-2 alpha-yl}morpholinium iodide, anchimerically assisted by keto carbonyl, and a Cannizzaro-type reaction of 3-(2-oxocyclohexyl)propanal, occurring via axial hydride transfer onto the cyclohexanone, are reported.
| Item Type: | Journal Article |
|---|---|
| Publication: | Journal of Chemical Research |
| Publisher: | Science Reviews 2000 Ltd |
| Additional Information: | Copyright of this article belongs to Science Reviews 2000 Ltd. |
| Department/Centre: | Division of Chemical Sciences > Organic Chemistry |
| Date Deposited: | 31 May 2011 06:14 |
| Last Modified: | 31 May 2011 06:14 |
| URI: | http://eprints.iisc.ac.in/id/eprint/38035 |
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