Mishra, AK and Bhattacharjee, B and Rangarajan, SK (1992) Theory of electron transfer processes via chemisorbed intermediates: Part II. Current-potential characteristics. In: Journal of Electroanalytical Chemistry, 331 (1-2). pp. 801-813.
![]() |
PDF
Theory_of_electron_transfer.pdf - Published Version Restricted to Registered users only Download (899kB) | Request a copy |
Abstract
Current-potential characteristics are obtained numerically for a lone-adsorbate-mediated anodic charge transfer at the electrode-solution interface. An increase in the overpotential leads to the appearance of maxima in the anodic current-potential plots instead of the extended activationless region (i.e. a saturation current at large positive overpotentials) predicted by the direct heterogeneous outer-sphere anodic charge transfer process. A detailed analysis of the dependence of current-potential profiles and other kinetic parameters on various system parameters is also presented.
Item Type: | Journal Article |
---|---|
Publication: | Journal of Electroanalytical Chemistry |
Publisher: | Elsevier science |
Additional Information: | Copyright of this article belongs to Elsevier science. |
Department/Centre: | Division of Chemical Sciences > Inorganic & Physical Chemistry |
Date Deposited: | 30 May 2011 05:38 |
Last Modified: | 30 May 2011 05:38 |
URI: | http://eprints.iisc.ac.in/id/eprint/37775 |
Actions (login required)
![]() |
View Item |