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First-Order Hyperpolarizabilities of Sulfophthalein Dyes

Ray, Paresh Chandra and Das, Puspendu Kumar (1995) First-Order Hyperpolarizabilities of Sulfophthalein Dyes. In: Journal of Physical Chemistry, 99 (39). pp. 14414-14417.

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Official URL: http://pubs.acs.org/doi/abs/10.1021/j100039a032


In this paper we report the first hyperpolarizabilities (beta) of 12, sulfophthalein dyes. Since these dyes are ionic in nature, their second-order nonlinearities were measured by the hyper-Rayleigh scattering technique in solution. The measured beta values are large and highly solvent dependent. Inclusion of solvent polarity in ab initio estimates of static second-order polarizability does not fully account for the experimental beta values. Contributions from the dissociated forms of the dye in different solvents seem to play an important role in enhancing beta in these systems.

Item Type: Journal Article
Publication: Journal of Physical Chemistry
Publisher: American Chemical Society
Additional Information: Copyright of this article belongs to American Chemical Society.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 18 May 2011 08:11
Last Modified: 18 May 2011 08:11
URI: http://eprints.iisc.ac.in/id/eprint/37745

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