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Synthetic approaches to homogynolides A and B

Srikrishna, Adusumili and Nagaraju, S and Reddy, TJ and Venkateswarlu, S (1996) Synthetic approaches to homogynolides A and B. In: Pure and Applied Chemistry, 68 (3). pp. 699-702.

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A four step, efficient and general methodology for the conversion of a cyclic ketone into the corresponding alpha-spiro-beta-methylene-gamma-butyrolactone, the key structural feature present in tricyclic sesquiterpenes bakkanes, has been developed employing a regiospecific 5-exo dig radical cyclisation reaction as the key step. The methodology has been extended to the total synthesis of bakkanes including homogynolide-B and chiral homogynolide-A.

Item Type: Journal Article
Publication: Pure and Applied Chemistry
Publisher: International Union of Pure and Applied Chemistry
Additional Information: Copyright of this article belongs to International Union of Pure and Applied Chemistry.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 31 May 2011 05:10
Last Modified: 31 May 2011 05:10
URI: http://eprints.iisc.ac.in/id/eprint/37622

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