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Synthesis and characterization of poly(vinyl acetate peroxide)

Jayanthi, S and Kishore, K (1996) Synthesis and characterization of poly(vinyl acetate peroxide). In: Journal of Applied Polymer Science, 59 (12). 1887 -1890 .

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Poly(vinyl acetate peroxide) (PVACP) was prepared from vinyl acetate by free-radical-initiated oxidative polymerization. The polyperoxide was isolated and characterized by different spectroscopic methods. The extreme instability of PVACP was demonstrated by FTIR spectroscopy. The H-1- and C-13-NMR studies show the irregularities in the polyperoxide chain due to the cleavage reactions of the propagating peroxide radical. Thermal degradation studies using differential scanning calorimetry revealed that PVACP degrades at a lower temperature and the heat of degradation is in the same range as reported for other vinyl polyperoxides. (C) 1996 John Wiley & Sons, Inc.

Item Type: Journal Article
Publication: Journal of Applied Polymer Science
Publisher: John Wiley and Sons
Additional Information: Copyright of this article belongs to John Wiley and Sons.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 13 May 2011 05:58
Last Modified: 13 May 2011 05:58
URI: http://eprints.iisc.ac.in/id/eprint/37604

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