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Reactivities of aluminium and aluminium-magnesium alloy powders in polymeric composites

Deevi, S and Deevi, SC and Verneker, VRP (1996) Reactivities of aluminium and aluminium-magnesium alloy powders in polymeric composites. In: Journal of Materials Science (full set), 31 (4). pp. 1043-1051.

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Polymeric compositions containing Al-Mg alloys show higher reactivities, in comparison with similar compositions containing aluminium. This is observed irrespective of the amount of oxidizer, type of oxidizer used, type of polymeric binder, and over a range of the particle sizes of the metal additive. This is evident from the higher calorimetric values obtained for compositions containing the alloy, in comparison to samples containing aluminium. Analysis of the combustion residue shows the increase in calorimetric value to be due to the greater extent of oxidation of the alloy. The interaction between the polymeric binder and the alloy was studied by coating the metal particles with the polymer by a coacervation technique. On ageing in the presence of ammonium perchlorate, cracking of the polymer coating on the alloy was noticed. This was deduced from differential thermal analysis experiments, and confirmed by scanning electron microscopic observations. The increase in stiffness of the coating, leading to cracking, has been traced to the cross-linking of the polymer by magnesium.

Item Type: Journal Article
Publication: Journal of Materials Science (full set)
Publisher: Springer
Additional Information: Copyright of this article belongs to Springer.
Department/Centre: Division of Chemical Sciences > Materials Research Centre
Date Deposited: 10 May 2011 07:44
Last Modified: 31 Jan 2019 09:02
URI: http://eprints.iisc.ac.in/id/eprint/37506

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