Ravikumar, KS and Chandrasekaran, S (1996) Reaction of diisopropoxytitanium(III) tetrahydroborate with selected organic compounds containing representative functional groups. In: Journal of Organic Chemistry, 61 (3). pp. 826-830.
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Official URL: http://pubs.acs.org/doi/abs/10.1021/jo951313t
Abstract
Diisopropoxytitanium(III) tetrahydroborate, ((PrO)-Pr-1)(2)TiBH4), generated in situ in dichloromethane from diisopropoxytitanium dichloride and benzyltriethylammonium borohydride in a 1:2 ratio selectively reduces aldehydes, ketones, acid chlorides, carboxylic acids, and N-Boc-protected amino acids to the corresponding alcohols in excellent yield under very mild reaction conditions (-78 to 25 degrees C).
| Item Type: | Journal Article |
|---|---|
| Publication: | Journal of Organic Chemistry |
| Publisher: | American Chemical Society |
| Additional Information: | Copyright of this article belongs to American Chemical Society. |
| Department/Centre: | Division of Chemical Sciences > Organic Chemistry |
| Date Deposited: | 10 May 2011 07:33 |
| Last Modified: | 10 May 2011 07:33 |
| URI: | http://eprints.iisc.ac.in/id/eprint/37505 |
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