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Primary pyrolysis products of thiokol liquid polysulfide

Ganesh, Kannan and Kishore, Kaushal (1996) Primary pyrolysis products of thiokol liquid polysulfide. In: Macromolecules, 29 (1). pp. 26-29.

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Official URL: http://pubs.acs.org/doi/abs/10.1021/ma9510451


An analysis of the primary degradation products of the widely used commercial polysulfide polymer Thiokol LP-33 by direct pyrolysis-mass spectrometry (DP-MS) is reported. The mechanism of degradation is through a radical process involving the random cleavage of a formal C-O bond followed by backbiting to form the cyclic products.

Item Type: Journal Article
Publication: Macromolecules
Publisher: American Chemical Society
Additional Information: Copyright of this article belongs to American Chemical Society.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 09 May 2011 10:44
Last Modified: 09 May 2011 11:06
URI: http://eprints.iisc.ac.in/id/eprint/37476

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