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Novel reduction (Zn-AcOH) of DDHQ esters - A new route to tropone synthesis

Kasturi, Tirumalai R and Palle, Pragnacharyulu VP and Sattigeri, Jitendra A and Kumar, Kaipenchery A (1996) Novel reduction (Zn-AcOH) of DDHQ esters - A new route to tropone synthesis. In: Tetrahedron, 52 (5). pp. 1707-1712.

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Official URL: http://dx.doi.org/10.1016/0040-4020(95)01006-8


Zn/acetic acid reaction of DDHQ esters 1 a-d gave the saturated acids 3 a-d and the hydrocarbons 7 a-d. The intermediacy of the aldehydes 10 and 11 in the formation of the products has been established. Oxidation of hydrocarbons 7a and 7b gave the corresponding tropones (5a and 5b).

Item Type: Journal Article
Publication: Tetrahedron
Publisher: Elsevier Science
Additional Information: Copyright of this article belongs to Elsevier Science.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 07 May 2011 04:49
Last Modified: 07 May 2011 04:49
URI: http://eprints.iisc.ac.in/id/eprint/37429

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