Kasturi, Tirumalai R and Palle, Pragnacharyulu VP and Sattigeri, Jitendra A and Kumar, Kaipenchery A (1996) Novel reduction (Zn-AcOH) of DDHQ esters - A new route to tropone synthesis. In: Tetrahedron, 52 (5). pp. 1707-1712.
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Official URL: http://dx.doi.org/10.1016/0040-4020(95)01006-8
Abstract
Zn/acetic acid reaction of DDHQ esters 1 a-d gave the saturated acids 3 a-d and the hydrocarbons 7 a-d. The intermediacy of the aldehydes 10 and 11 in the formation of the products has been established. Oxidation of hydrocarbons 7a and 7b gave the corresponding tropones (5a and 5b).
| Item Type: | Journal Article |
|---|---|
| Publication: | Tetrahedron |
| Publisher: | Elsevier Science |
| Additional Information: | Copyright of this article belongs to Elsevier Science. |
| Department/Centre: | Division of Chemical Sciences > Organic Chemistry |
| Date Deposited: | 07 May 2011 04:49 |
| Last Modified: | 07 May 2011 04:49 |
| URI: | http://eprints.iisc.ac.in/id/eprint/37429 |
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