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Solubilities of Benzene Derivatives in Supercritical Carbon Dioxide

Reddy, Sivamohan N and Madras, Giridhar (2011) Solubilities of Benzene Derivatives in Supercritical Carbon Dioxide. In: Journal of Chemical & Engineering Data J Chem Eng Data, 56 (4). pp. 1695-1699.

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Official URL: http://pubs.acs.org/doi/abs/10.1021/je100863p


The solubilities of benzene derivatives in supercritical carbon dioxide was determined by the saturation method over the pressure range (9.5 to 14.5) MPa. The solubilities were determined at (308 and 313) K for 1-chloro-2,4-dinitrobenzene and (308, 318, and 328) K for m-dinitrobenzene. At 308K, the solubility (in mole fraction) of 1-chloro-2,4-dinitrobenzene varied from (2.83 to 5.88).10(-3) while the solubility of m-dinitrobenzene increased from (2.05 to 5.54).10(-3) as the pressure increased from (9.5 to 14.5) MPa. However, the solubilities of both compounds decreased with increasing temperature. Models based on the solubility parameter and semiempirical models such as the Mendez-Santiago-Teja model, the Gordillo model, and the association model, were used to correlate the experimental solubility data for the benzene derivatives.

Item Type: Journal Article
Publication: Journal of Chemical & Engineering Data J Chem Eng Data
Publisher: American Chemical Society
Additional Information: Copyright of this article belongs to American Chemical Society.
Department/Centre: Division of Mechanical Sciences > Chemical Engineering
Date Deposited: 06 May 2011 05:53
Last Modified: 06 May 2011 05:53
URI: http://eprints.iisc.ac.in/id/eprint/37382

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