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Mechanism of ?-cleavage in the excited states of keto sulfides

Raman, Sumathi and Asish, Chandra K (1992) Mechanism of ?-cleavage in the excited states of keto sulfides. In: Perkin Transactions 2 (2). pp. 291-294.

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The beta-cleavage process in photoexcited ketones of structure RCOCH2X (X = CH2CH3, OCH3, SCH3; R = CH3, Ph) has been studied using the configuration interaction procedure within the framework of MINDO/3. The results explain qualitatively why the beta-cleavage process is faster than the alpha-cleavage process in keto sulfides while in keto ethers the reverse is true.

Item Type: Journal Article
Publication: Perkin Transactions 2
Publisher: Royal Soc Chemistry
Additional Information: Copyright of this article belongs to Royal Soc Chemistry.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 05 May 2011 06:14
Last Modified: 26 Feb 2019 08:47
URI: http://eprints.iisc.ac.in/id/eprint/37214

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