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(+/-)-cis-Dichloro[P-(isopropylamino)-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine](triethylphosphine)platinum(II) dichloromethane solvate

Parvez, M and Babu, RPK and Krishnamurthy, SS (1996) (+/-)-cis-Dichloro[P-(isopropylamino)-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine](triethylphosphine)platinum(II) dichloromethane solvate. In: Acta Crystallographica Section C, 52 (part 2). pp. 333-336.

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In the racemic title compound, [PtCl2(C23H20NO2P)-(C6H15P)].CH2Cl2, the platinum(II) ion, which has approximately square-planar coordination geometry, is coordinated to two different monophosphorus ligands in a cis arrangement along with two chloride ions. A significant shortening of the P-N bond [1.604(7) Angstrom] relative to that in phosphinoamines and their complexes was observed.

Item Type: Journal Article
Publication: Acta Crystallographica Section C
Publisher: International union of crystallography
Additional Information: Copyright of this article belongs to International union of crystallography.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 21 Apr 2011 05:57
Last Modified: 21 Apr 2011 05:57
URI: http://eprints.iisc.ac.in/id/eprint/37071

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