Chemo- and stereoselective reduction of alpha,beta-epoxyketones with diisopropoxytitanium(III) tetrahydroborate

Ravikumar, KS and Chandrasekaran, Srinivasan (1996) Chemo- and stereoselective reduction of alpha,beta-epoxyketones with diisopropoxytitanium(III) tetrahydroborate. In: Tetrahedron, 52 (27). pp. 9137-9142.

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Abstract

Reduction of alpha,beta-epoxyketones with diisopropoxytitanium(III) tetrahydroborate in dichloromethane under mild conditions (-78 degrees--> -20 degrees C) provides anti- (or erythro-) alpha,beta-epoxy alcohols in high yields with high degree of chemo- and stereoselectivity. Copyright (C) 1996 Elsevier Science Ltd

Item Type:	Journal Article
Publication:	Tetrahedron
Publisher:	Elsevier science
Additional Information:	Copyright of this article belongs to Elsevier science.
Department/Centre:	Division of Chemical Sciences > Organic Chemistry
Date Deposited:	21 Apr 2011 05:33
Last Modified:	21 Apr 2011 05:33
URI:	http://eprints.iisc.ac.in/id/eprint/37069

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