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Total synthesis of the novel sesquiterpenes of Eremophila georgei Diels

Selvakumar, Natesan and Rao, Subba GSR (1994) Total synthesis of the novel sesquiterpenes of Eremophila georgei Diels. In: Journal of the Chemical Society - Series Chemical Communications (11). pp. 1303-1304.

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Abstract

The first stereoselective total synthesis of the natural sesquiterpenes 4 and 5, having the tricyclo[6.2.1.0(1,5)]undecane skeleton with a bridgehead methyl group, is reported via the intermediate 9, which was obtained by the acid catalysed rearrangement of the alcohols 7 and 8.

Item Type: Journal Article
Publication: Journal of the Chemical Society - Series Chemical Communications
Publisher: Royal society of chemistry
Additional Information: Copyright of this article belongs to Royal society of chemistry.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 16 Apr 2011 12:32
Last Modified: 16 Apr 2011 12:32
URI: http://eprints.iisc.ac.in/id/eprint/36915

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