Chandrasekaran, Annamalai and Krishnamurthy, Setharampattu S and Nethaj, Munirathinam (1994) Studies of phosphazenes. Part 34. group 6 metal carbonyl complexes of bis(pyrazolyl)cyclotriphosphazenes. In: Dalton Transactions (1). pp. 63-68.
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Abstract
Reactions of the bis(3,5-dimethylpyrazol-1-yl)cyclotriphosphazenes gem-N3P3Ph4(C3HN2Me2)2 (L1) and N3P3(MeNCH2CH2O)2(C3HN2Me2)2 (L2) with [M(CO)6] (M = Mo or W) afford complexes of the type [M(CO)3L] (L = L1 or L2), which have been characterised by IR and NMR spectroscopic data. The structures of [Mo(CO)3L1], [W(CO)3L2] and the ligand L2 have been determined by single-crystal X-ray diffraction. The phosphazenes act as novel tridentate NNN-donor ligands with two pyrazolyl nitrogen atoms and one phosphazene ring nitrogen atom bonded to the metal atom
Item Type: | Journal Article |
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Publication: | Dalton Transactions |
Publisher: | Royal society of chemistry |
Additional Information: | Copyright of this article belongs to Royal society of chemistry. |
Department/Centre: | Division of Chemical Sciences > Inorganic & Physical Chemistry |
Date Deposited: | 13 Apr 2011 06:54 |
Last Modified: | 13 Apr 2011 06:54 |
URI: | http://eprints.iisc.ac.in/id/eprint/36841 |
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