Organometallics of diphosphazanes. Part 10. Dinuclear group 6 metal carbonyl complexes bridged by a cyclodiphosphazane in its cis or trans form

Reddy, Venkata S and Krishnamurthy, Setharampattu S and Nethaji, Munirathinam (1994) Organometallics of diphosphazanes. Part 10. Dinuclear group 6 metal carbonyl complexes bridged by a cyclodiphosphazane in its cis or trans form. In: Dalton Transactions (18). pp. 2661-2667.

PDF Organometallics_of_Diphosphazanes..pdf - Published Version Restricted to Registered users only Download (866kB) | Request a copy

Abstract

Mononuclear Group 6 metal tetracarbonyl complexes containing a cyclodiphosphazane ligand, [PhNP(OC(6)H(4)Me-p)](2) (L), have been used as synthons to prepare homo- and hetero-bimetallic complexes in which the cyclodiphosphazane bridges the two metal centres in its cis or trans isomeric forms. The dimolybdenum complex [Mo-2(eta(5)-C5H5)(2)(CO)(4)(mu-L)] has also been synthesized. The trends in P-31 NMR chemical shifts and the structural features as revealed by X-ray crystallography are discussed.

Item Type:	Journal Article
Publication:	Dalton Transactions
Publisher:	Royal society of chemistry
Additional Information:	Copyright of this article belongs to Royal society of chemistry.
Department/Centre:	Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited:	08 Apr 2011 10:34
Last Modified:	08 Apr 2011 10:34
URI:	http://eprints.iisc.ac.in/id/eprint/36668

Actions (login required)

View Item