Uma, S and Das, PK (1994) Dynamics of I-asterisk(P-2(1/2)) production inthe ultraviolet photodissociation of alkyn iodides. In: Canadian journal of chemistry / revue canadienne de chimie, 72 (3). 865-869 .
Full text not available from this repository. (Request a copy)Abstract
The relative quantum yields, phi*, for the production of I*(P-2(1/2)) at 266, 280, and similar to 305 nm are reported for a series of primary alkyl iodides using the technique of two-photon laser-induced fluorescence for the detection of I(P-2(3/2)) and I*(P-2(1/2)) atoms. Results are analyzed by invoking the impulsive energy disposal model, which summarizes the dynamics of dissociation as a single parameter. Comparison of our data with those calculated by a more sophisticated time-dependent quantum mechanical model is also made. Near the red edge of the alkyl iodide A band, absorption contribution from the (3)Q(1) state is important and the dynamics near the (3)Q(0)-(1)Q(1) curve-crossing region seem to be influenced by the kinematics of the dissociation process
| Item Type: | Journal Article |
|---|---|
| Publication: | Canadian journal of chemistry / revue canadienne de chimie |
| Publisher: | NRC research press |
| Additional Information: | Copyright of this article belongs to NRC research press. |
| Department/Centre: | Division of Chemical Sciences > Inorganic & Physical Chemistry |
| Date Deposited: | 01 Jun 2011 06:33 |
| Last Modified: | 01 Jun 2011 06:33 |
| URI: | http://eprints.iisc.ac.in/id/eprint/36422 |
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