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Construction of energy-level diagram of oriented benzene using connectivity information obtained by modified z-cosy experiment

Grace, RCR and Kumar , S (1994) Construction of energy-level diagram of oriented benzene using connectivity information obtained by modified z-cosy experiment. In: Proceedings of the Indian Academy of Sciences - Chemical Sciences, 106 (7). pp. 1463-1469.

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Abstract

Experiments involving selective perturbation of a transition yield information about the directly connected transitions, which in turn yield information for deriving the parameters of the spin Hamiltonian of oriented molecules. Problems involved with selective perturbation are removed by the use of a two-dimensional experiment, namely, the modified Z-COSY-experiment, The use of this experiment is demonstrated for obtaining the connectivity information and for determining the parameters of the spin Hamiltonian of oriented benzene, a strongly coupled six-spin system

Item Type: Journal Article
Publication: Proceedings of the Indian Academy of Sciences - Chemical Sciences
Publisher: Indian academy of sciences
Additional Information: Copyright of this article belongs to Indian academy of sciences.
Department/Centre: Division of Physical & Mathematical Sciences > Physics
Date Deposited: 26 Mar 2011 05:24
Last Modified: 26 Mar 2011 05:24
URI: http://eprints.iisc.ac.in/id/eprint/36307

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