Balasubramanian, KK and Ramesh,, NG and Pramanik, A and Chandrasekhar, Jayaraman (1994) Aromatic claisen rearrangements in carbohydrates: stereocontrol of rearrangement rates in unsaturated sugar substrates. In: Perkin Transactions 2 (7). 1399 -1401.
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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/1994...
Abstract
A remarkable difference is observed in the rates of [3,3]-sigmatropic rearrangement of aryl 4,6-di-O-acetyl-2,3-dideoxy-D-erythro-hex-2-enopyranosides 1 and 2; the slower reactivity of the alpha-isomers is consistent with AM1 calculated transition state energetics of model systems.
| Item Type: | Journal Article |
|---|---|
| Publication: | Perkin Transactions 2 |
| Publisher: | Royal Society of Chemistry. |
| Additional Information: | Copyright of this article belongs to Royal Society of Chemistry. |
| Department/Centre: | Division of Chemical Sciences > Organic Chemistry |
| Date Deposited: | 26 Mar 2011 06:21 |
| Last Modified: | 26 Mar 2011 06:21 |
| URI: | http://eprints.iisc.ac.in/id/eprint/36244 |
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