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A facile entry to macrocyclic disulfides: an efficient synthesis of redox-switched crown ethers

Ramesha, AR and Chandrasekaran, S (1994) A facile entry to macrocyclic disulfides: an efficient synthesis of redox-switched crown ethers. In: Journal of Organic Chemistry, 59 (6). 1354 -1357.

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Official URL: http://pubs.acs.org/doi/abs/10.1021/jo00085a025

Abstract

An interesting sulfur transfer reaction with benzyltriethylammonium tetrathiomolybdate has been used efficiently for the synthesis of macrocyclic disulfides. This methodology has been extended to a high-yield synthesis of ''redox-switched'' crown ethers which have potential application for selective ion transport across liquid membranes.

Item Type: Journal Article
Publication: Journal of Organic Chemistry
Publisher: American Chemical Society
Additional Information: Copyright of this article belongs to American Chemical Society.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 03 Jun 2011 07:22
Last Modified: 03 Jun 2011 07:22
URI: http://eprints.iisc.ac.in/id/eprint/36111

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