Stereoelectronic control of Cope rearrangement energetics through remote double bonds in novel, rigid polycyclic frames

Mehta, Goverdhan and Reddy, Hari Krishna S and Pattabhi, Vasantha and Bhanumathi, S and Pramanik, Animesh and Chandrasekhar, Jayaraman (1993) Stereoelectronic control of Cope rearrangement energetics through remote double bonds in novel, rigid polycyclic frames. In: Perkin Transactions 1 (14). pp. 1539-1541.

PDF Cope.pdf - Published Version Restricted to Registered users only Download (316kB) | Request a copy

Abstract

The presence and orientation of remote double bonds are shown to completely alter the shapes of Cope rearrangement energy profiles in a heptacyclic system.

Item Type:	Editorials/Short Communications
Publication:	Perkin Transactions 1
Publisher:	Royal Society of Chemistry
Additional Information:	Copyright of this article belongs to Royal Society of Chemistry.
Department/Centre:	Division of Chemical Sciences > Organic Chemistry
Date Deposited:	25 Feb 2011 07:06
Last Modified:	25 Feb 2011 07:06
URI:	http://eprints.iisc.ac.in/id/eprint/35764

Actions (login required)

View Item