A porphyrin bearing tetrahydrothiophene pickets; co-ordination behaviour and electron transfer

D'Souza , Francis and Krishnan, Varadachari (1992) A porphyrin bearing tetrahydrothiophene pickets; co-ordination behaviour and electron transfer. In: Dalton Transactions (19). 2873 -2876.

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Abstract

A novel ‘picket-fence’ porphyrin, 5,10,15,20-tetrakis[o-(tetrahydro-2-thenoylamino)phenyl]porphyrin (H2L) with ligating tetrahydrothiophene rings disposed perpendicular to the porphyrin plane has been synthesised. Its zinc(II) derivative, [ZnL], binds two silver(I) ions co-operatively with a dissociation constant of 4.8 × 10–8 dm3 mol–1. Time-resolved fluorescence lifetime measurements reveal the presence of intramolecular photoexcited electron transfer in this donor–acceptor system.

Item Type:	Journal Article
Publication:	Dalton Transactions
Publisher:	Royal Society of Chemistry
Additional Information:	Copyright of this article belongs to Royal Society of Chemistry.
Department/Centre:	Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited:	28 Jan 2011 04:57
Last Modified:	28 Jan 2011 04:57
URI:	http://eprints.iisc.ac.in/id/eprint/35085

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