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Synthetic and physicochemical studies of uranium complexes with semicarbazone and hydrazone

Agarwala, BV and Hingorani, S and Gowda, Nagana GA (1990) Synthetic and physicochemical studies of uranium complexes with semicarbazone and hydrazone. In: Inorganica Chimica Acta, 176 (1). pp. 149-154.

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Official URL: http://dx.doi.org/10.1016/S0020-1693(00)85106-3


Uranyl complexes of two Schiff bases, semicarbazone and hydrazone containing OON donor atoms have been synthesized and characterized on the basis of NMR, IR and electronic spectral studies, conductance, magnetic susceptibility and thermogravimetric data. The 1H NMR spectrum of the semicarbazone complex shows low field signals due to OH, NH and ---CH=N groups at 10.23, 9.31 and 8.17 ppm, respectively. The aromatic protons appear in the range 7.74–7.40 ppm. On complexation with U(VI) the signals due to OH and NH disappear evidently due to their participation in coordination. The coordination number of the o-vanillin semicarbazone (oVSC) complex is 6 whereas, that of the o-vanillin isonicotinic acid hydrazone (oVINAH) complex is 8, in addition to the two oxygen atoms already bonded to U(VI) in each species. The thermograms show the presence of 3 and 2 water molecules in these complexes, respectively and the IR spectral data also support the above conclusion. Suitable structures have been assigned.

Item Type: Journal Article
Publication: Inorganica Chimica Acta
Publisher: Elsevier Science
Additional Information: Copyright of this article belongs to Elsevier Science.
Department/Centre: Division of Chemical Sciences > Sophisticated Instruments Facility (Continued as NMR Research Centre)
Date Deposited: 11 Jan 2011 07:07
Last Modified: 11 Jan 2011 07:07
URI: http://eprints.iisc.ac.in/id/eprint/34937

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