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A Study of copper-compounds by x-Ray Absorption-spectroscopy

Murugesan, T and Sarode, PR and Gopalakrishnan, J and Rao, CNR (1980) A Study of copper-compounds by x-Ray Absorption-spectroscopy. In: Dalton Transactions (5). pp. 837-839.

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Chemical shifts, ΔE, of the K-absorption discontinuity in several compounds of copper possessing formal oxidation states between 0 and III have been measured. The shifts show a parabolic dependence on the formal oxidation state as well as on the effective atomic charge, q, on copper. Anomalous chemical shifts shown by some of the compounds are discussed in terms of the bonding in these compounds. The ΔE values have also been correlated with the core electron binding energies obtained from X-ray photoelectron spectroscopy.

Item Type: Journal Article
Publication: Dalton Transactions
Publisher: Royal Society of Chemistry
Additional Information: Copyright of this article belongs to Royal Society of Chemistry.
Department/Centre: Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Date Deposited: 05 Jan 2011 08:49
Last Modified: 05 Jan 2011 08:49
URI: http://eprints.iisc.ac.in/id/eprint/34840

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