Kumar , Sreenivasa KR and Nethaji , M and Patil, KC (1991) Synthesis, Characterization and Structure of (N2H5)3MnX5 (X = Cl and Br). In: Journal of Coordination Chemistry, 24 (4). 333 -337.
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Abstract
Two new hydrazinium complexes of manganese, (N2H5)3MnX5 (X = Cl and Br), have been prepared and characterized by analysis, infrared and visible spectra. The single crystal X-ray structure of the chloride complex has been determined. Only one of the three N2H+5 cations is coordinated to the metal. In the anion, [Mn(N2H5)Cl5]2-, the coordination polyhedron around the manganese atom is a slightly distorted octahedron.
Item Type: | Journal Article |
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Publication: | Journal of Coordination Chemistry |
Publisher: | Taylor and Francis Group |
Additional Information: | Copyright of this article belongs to Taylor and Francis Group. |
Keywords: | Hydrazinium cation;manganese complex;X-ray structure. |
Department/Centre: | Division of Chemical Sciences > Inorganic & Physical Chemistry |
Date Deposited: | 14 Dec 2010 05:30 |
Last Modified: | 14 Dec 2010 05:30 |
URI: | http://eprints.iisc.ac.in/id/eprint/34192 |
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