Kishore, K and Kannan, P and Iyanar, K (1991) Synthesis, characterization, and fire retardancy of ferrocene containing polyphosphate esters. In: Journal of Polymer Science Part A: Polymer Chemistry, 29 (7). 1039 -1044.
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Abstract
Polyphosphate esters containing ferrocene structures were synthesized from 1,1′-bis (p-hydroxyphenylamido) ferrocene and 1,1′-bis (p-hydroxyphenoxycarbonyl) ferrocene with aryl phosphorodichloridates by interfacial polycondensation using a phase transfer catalyst. The polymers were characterized by infrared, 1H-, 13C-, and 31-NMR spectroscopy. The molecular weights were determined by end group analysis using 31P-NMR spectral data. The thermal stability and fire retardancy were respectively determined by thermogravimetry and limiting oxygen index (LOI) measurements. The polyamide-phosphate esters showed better thermal stability and higher LOI values than the polyester-phosphate esters.
Item Type: | Journal Article |
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Publication: | Journal of Polymer Science Part A: Polymer Chemistry |
Publisher: | John Wiley & Sons |
Additional Information: | Copyright of this article belongs to John Wiley & Sons. |
Department/Centre: | Division of Chemical Sciences > Inorganic & Physical Chemistry |
Date Deposited: | 14 Dec 2010 05:33 |
Last Modified: | 14 Dec 2010 05:33 |
URI: | http://eprints.iisc.ac.in/id/eprint/34190 |
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