Ramanathan, H and Rao, GSRS (1991) Synthesis Based On Cyclohexadienes .6. A New Total Synthesis Of (+/-)-Methyl Acorate And (+/-)-Methyl Epi-Acorate. In: Indian Journal of Chemistry - Section B: Organic and Medicinal Chemistry, 30 (10). pp. 901-910.
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Abstract
A new method of construction of carbon-carbon bond is described. Thus the dianions generated from the metal-ammonia reduction of substituted benzoic acids readily undergo Michael addition with methyl crotonate resulting in synthetically useful products having a quaternary carbon. Based on this strategy, new syntheses of (+/-)-methyl acorate (14b) and (+/-)-methyl epi-corate (15) are reported.
| Item Type: | Journal Article |
|---|---|
| Publication: | Indian Journal of Chemistry - Section B: Organic and Medicinal Chemistry |
| Publisher: | National Institute of Science Communication and Information Resources |
| Additional Information: | Copyright of this article belongs to National Institute of Science Communication and Information Resources. |
| Department/Centre: | Division of Chemical Sciences > Organic Chemistry |
| Date Deposited: | 07 Dec 2010 09:47 |
| Last Modified: | 07 Dec 2010 09:47 |
| URI: | http://eprints.iisc.ac.in/id/eprint/34189 |
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