Deviation from Arrhenius behaviour of rate of intercage diffusion in Zeolite $Y^{1}$

Santikary, Prakriteswar and Yashonath, Subramanian (1996) Deviation from Arrhenius behaviour of rate of intercage diffusion in Zeolite $Y^{1}$. In: Electronic Journal of Theoretical Chemistry, 1 . pp. 87-92.

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Abstract

Rate of intercage diffusion (kc) along with rate of cage visits (kv) and diffusion coefficient (D) of sorbates in zeolite Y have been calculated. We show that as a consequence of the dependence of rate of intercage diffusion on short-time behaviour, significant deviation from the Arrhenius behaviour at suffciently high temperatures occurs.

Item Type:	Journal Article
Publication:	Electronic Journal of Theoretical Chemistry
Publisher:	JohnWiley & Sons, Ltd.
Additional Information:	The copyright belongs to John Wiley & Sons, Ltd.The DOI is currently only displayed.
Keywords:	diffusion;arrhenius law;zeolite y;molecular dynamics
Department/Centre:	Division of Interdisciplinary Sciences > Supercomputer Education & Research Centre Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Date Deposited:	27 Jul 2005
Last Modified:	19 Sep 2010 04:19
URI:	http://eprints.iisc.ac.in/id/eprint/3418

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