Structure of the rhenium X-ray LIII absorption edge in caesium hexachlororhenate(IV)

Sarode, PR (1979) Structure of the rhenium X-ray LIII absorption edge in caesium hexachlororhenate(IV). In: Dalton Transactions (6). pp. 993-995.

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Abstract

The X-ray LIII absorption-edge structure of rhenium in Cs2[ReCl6] has been measured with a bent-crystal X-ray spectrograph. An analysis in terms of molecular-orbital (m.o.) theory has been attempted. The energies of the m.o. levels, crystal-field splitting parameter, effective magnetic moment, magnetic susceptibility, and Landég parameter have been determined from this analysis. An estimate of the Re–Cl bond length has also been made.

Item Type:	Journal Article
Publication:	Dalton Transactions
Publisher:	Royal Society of Chemistry
Additional Information:	Copyright of this article belongs to Royal Society of Chemistry.
Department/Centre:	Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Date Deposited:	28 Dec 2010 06:42
Last Modified:	28 Dec 2010 06:42
URI:	http://eprints.iisc.ac.in/id/eprint/33930

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