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N-2-(4-Methyl-2-quinolyl)phenyl]acetamide: a P1 structure with Z=4

Khan, Nawaz F and Roopan, Mohana S and Malathi, N and Hathwar, Venkatesha R and Akkurt, Mehmet (2010) N-2-(4-Methyl-2-quinolyl)phenyl]acetamide: a P1 structure with Z=4. In: Acta Crystallographica Section E, 66 (Part 8). O2043-U1435.

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Official URL: http://scripts.iucr.org/cgi-bin/paper?pv2303


The title compound, C18H16N2O, crystallizes in the triclinic space group P1, with four independent molecules in the asymmetric unit wherein two molecules have an irregular -ac, -ac, +ap conformation (ap, antiperiplanar; ac, anticlinal), while the other molecules exhibit a different, +ac, +ac, +ap conformation. The planar (r.m.s. deviation = 0.006 A in each of the four molecules) quinoline ring systems of the four molecules are oriented at dihedral angles of 32.8 (2), 33.4 (2), 31.7 (2) and 32.3 (2)degrees with respect to the benzene rings. Intramolecular N-H...N interactions occur in all four independent molecules. The crystal packing is stabilized by intermolecular N-H...O and C-H...O hydrogen bonds, and are further consolidated by C-H...pi and pi-pi stacking interactions centroid-centroid distances = 3.728 (3), 3.722 (3), 3.758 (3) and 3.705 (3) A].

Item Type: Journal Article
Publication: Acta Crystallographica Section E
Publisher: International Union of Crystallography
Additional Information: Copyright of this article belongs to International Union of Crystallography.
Department/Centre: Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Date Deposited: 28 Oct 2010 06:13
Last Modified: 28 Oct 2010 06:13
URI: http://eprints.iisc.ac.in/id/eprint/33464

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