Chiral gels derived from secondary ammonium salts of (1R, 3S)-(+)-camphoric acid

Adalder, Tapas Kumar and Adarsh, NN and Sankolli, Ravish and Dastidar, Parthasarathi (2010) Chiral gels derived from secondary ammonium salts of (1R, 3S)-(+)-camphoric acid. In: Beilstein Journal of Organic Chemistry, 6 . pp. 848-858.

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Abstract

In order to have access to chiral gels, a series of salts derived from (1R, 3S)-(+)-camphoric acid and various secondary amines were prepared based on supramolecular synthon rationale. Out of seven salts prepared, two showed moderate gelation abilities. The gels were characterized by differential scanning calorimetry, table top rheology, scanning electron microscopy, single crystal and powder X-ray diffraction. Structure property correlation based on X-ray diffraction techniques remain inconclusive indicating that some of the integrated part associated with the gelation phenomena requires a better understanding.

Item Type:	Journal Article
Publication:	Beilstein Journal of Organic Chemistry
Publisher:	BioMed Central
Additional Information:	Copyright of this article belongs to BioMed Central.
Keywords:	Crystal engineering;LMOG;single crystal X-ray diffraction; supramolecular gels;supramolecular synthon.
Department/Centre:	Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Date Deposited:	27 Oct 2010 06:28
Last Modified:	24 Feb 2012 09:21
URI:	http://eprints.iisc.ac.in/id/eprint/33453

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