Gunasundari, Thanikachalam and Chandrasekaran, Srinivasan (2010) Enantioselective and Protecting Group-Free Synthesis of 1-Deoxythionojirimycin, 1-Deoxythiomannojirimycin, and 1-Deoxythiotalonojirimycin. In: Journal of Organic Chemistry, 75 (19). pp. 6685-6688.
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Official URL: http://pubs.acs.org/doi/abs/10.1021/jo1010125
Abstract
1-Deoxythioglyconojirimycins were synthesized by using a protecting group-free strategy, starting from readily available carbohydrates, in good overall yield. Use of benzyl-triethylammonium tetrathiomolybdate, BnEt3N](2)MoS4, as a sulfur transfer reagent and borohydride exchange resin (BER) reduction of a lactone enabled the efficient synthesis of the title compounds.
Item Type: | Journal Article |
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Publication: | Journal of Organic Chemistry |
Publisher: | American Chemical Society |
Additional Information: | Copyright of this article belongs to American Chemical Society. |
Department/Centre: | Division of Chemical Sciences > Organic Chemistry |
Date Deposited: | 18 Oct 2010 07:48 |
Last Modified: | 18 Oct 2010 07:48 |
URI: | http://eprints.iisc.ac.in/id/eprint/33132 |
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