Enantioselective total synthesis of polyoxygenated cyclohexanoids:(+)-streptol, ent-RKTS-33 and putative '(+)-parasitenone'. Identity ofparasitenone with (+)-epoxydon

Mehta, Goverdhan and Pujar, Shashikant R and Ramesh, Senaiar S and Islam, Kabirul (2005) Enantioselective total synthesis of polyoxygenated cyclohexanoids:(+)-streptol, ent-RKTS-33 and putative '(+)-parasitenone'. Identity ofparasitenone with (+)-epoxydon. In: Tetrahedron Letters, 46 (19). pp. 3373-3376.

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Abstract

Short, simple and enantioselective syntheses of the natural product(+)-streptol, the non-peptide apoptosis inhibitor ent-RKTS-33 and theputative structure of 'parasitenone' have been accomplished from thereadily available chiral building block. 'Parasitenone' has been shownto be identical with the known natural product epoxydon.

Item Type:	Journal Article
Publication:	Tetrahedron Letters
Publisher:	Pergamon-Elsevier Science Ltd
Additional Information:	Copyright for this article belongs to Elsevier.
Department/Centre:	Division of Chemical Sciences > Organic Chemistry
Date Deposited:	26 May 2005
Last Modified:	19 Sep 2010 04:19
URI:	http://eprints.iisc.ac.in/id/eprint/3246

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