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Total synthesis ofdl-9(11)-dehydrotestosterone anddl-testosterone

Banerjee, DK and Damodaran, KM and Murthy, PSN and Paul, V (1978) Total synthesis ofdl-9(11)-dehydrotestosterone anddl-testosterone. In: Journal of Chemical Sciences, 87 (8). 239 -246.

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17β-Hydroxy-des-A-androst-9-en-5-one (II, R=OH), prepared fromtrans-1β-hydroxy-8-methyl-4, 5-(3′-methyl-4′-methoxybenzo)-hydrindane (I, R=CH3)′, has been converted intodl-9(II)-dehydrotestosterone (IV, R=OH) anddl-testosterone (IX) in very short sequences of steps, albeit in poor yields.

Item Type: Journal Article
Publication: Journal of Chemical Sciences
Publisher: Indian Academy of Sciences
Additional Information: Copyright of this article belongs to Indian Academy of Sciences.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 27 Sep 2010 11:51
Last Modified: 27 Sep 2010 11:51
URI: http://eprints.iisc.ac.in/id/eprint/32454

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