2,4-Lutidine-1-oxide complexes of lanthanide perchlorates

Navaneetham, NS and Soundararajan, S (1979) 2,4-Lutidine-1-oxide complexes of lanthanide perchlorates. In: Proceedings of the Indian Academy of Sciences - Section A, 88 (2). pp. 131-135.

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Abstract

2,4-Lutidine-1-oxide (2,4-LutO) complexes of lanthanide perchlorates of the formulae Ln2(2,4-LutO)13(ClO4)6 (Ln = Pr and Nd) and Ln2(2,4-LutO)15 (ClO4)6 (Ln = La, Tb, Dy, Ho and Yb) have been prepared and characterised by chemical analysis, IR, NMR, conductance and electronic spectral data. Proton NMR data along with the IR data show that the ligand coordinates to the metal ion through the oxygen. Conductance data of the complexes in acetone and nitrobenzene indicate that the perchlorate is not coordinated to the metal ion.

Item Type:	Journal Article
Publication:	Proceedings of the Indian Academy of Sciences - Section A
Publisher:	Springer
Additional Information:	Copyright of this article belongs to Springer.
Keywords:	Lanthanide perch/orates; 2,4-Lutidine.l-oxide; hypersensitive bands,
Department/Centre:	Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited:	21 Sep 2010 10:09
Last Modified:	21 Sep 2010 10:09
URI:	http://eprints.iisc.ac.in/id/eprint/32210

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