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An ultraviolet photoelectron spectroscopic study of BF3–donor complexes

Pradeep, T and Sreekanth, CS and Rao, CNR (1989) An ultraviolet photoelectron spectroscopic study of BF3–donor complexes. In: Journal of Chemical Physics, 90 (9). pp. 4704-4708.

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He i spectra of strong n–v type adducts of BF3 with H2O, CH3OH, (C2H5)2O, and CH3CN as well as of weak complexes of BF3 with NO and H2S are reported along with assignments based on MO calculations. The energy of the fluorine orbitals of BF3 is shown to be shifted in proportion to the strength of the donor–acceptor interaction. BF3 seems to form a contact pair with CS2.

Item Type: Journal Article
Publication: Journal of Chemical Physics
Publisher: American Institute of Physics
Additional Information: Copyright of this article belongs to American Institute of Physics.
Department/Centre: Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Date Deposited: 24 Aug 2010 10:56
Last Modified: 19 Sep 2010 06:14
URI: http://eprints.iisc.ac.in/id/eprint/31507

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