Anil, Kumar R and Chandrasekhar, Sosale (2000) An environment-friendly Beckmann rearrangement: the diazotisation of ketoxime carbamates. In: Tetrahedron Letters, 41 (37). pp. 7235-7237.
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Official URL: http://dx.doi.org/10.1016/S0040-4039(00)01243-0
Abstract
The titled reaction was effected with iso-amyl nitrite or sodium nitrite, both in cone. H2SO4 at 0-25 degrees C in excellent yields (55-98%). Apart from the mild temperatures employed, organic solvents and reagents can be avoided, and the by-products are CO2 and N-2, so the conditions are environment-friendly. (C) 2000 Elsevier Science Ltd. All rights reserved.
| Item Type: | Journal Article |
|---|---|
| Publication: | Tetrahedron Letters |
| Publisher: | Elsevier science |
| Additional Information: | Copyright of this article belongs to Elsevier science. |
| Department/Centre: | Division of Chemical Sciences > Organic Chemistry |
| Date Deposited: | 04 Aug 2010 10:27 |
| Last Modified: | 21 Feb 2019 09:06 |
| URI: | http://eprints.iisc.ac.in/id/eprint/31123 |
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