Biju, John P and Kaliappan, Krishna and Laxmisha, MS and Rao, Subba GSR (2000) Synthesis based on cyclohexadienes. Part 34. A tandem cationic rearrangement-ene cyclisation route to 2-pupukeanone. In: Perkin 1 (22). pp. 3714-3718.
![[img]](http://eprints.iisc.ac.in/style/images/fileicons/application_pdf.png) |
PDF
tandem.pdf - Published Version Restricted to Registered users only Download (111kB) | Request a copy |
Official URL: http://www.rsc.org/publishing/journals/P1/article....
Abstract
A new strategy for the construction of the isotwistane skeleton is reported from easily available cyclohexadienes, which involves a one-pot cationic skeletal rearrangement and ene cyclisation of a bicyclo[2.2.2]octenone derivative and a cationic rearrangement of a tricyclo[5.3.0.0(4,8)]decane to a [4.3.1.0(3,7)]decane skeleton as the key steps in the synthesis of 2-pupukeanone.
| Item Type: | Journal Article |
|---|---|
| Publication: | Perkin 1 |
| Publisher: | Royal Society of Chemistry |
| Additional Information: | Copyright of this article belongs to Royal Society of Chemistry. |
| Department/Centre: | Division of Chemical Sciences > Organic Chemistry |
| Date Deposited: | 04 Aug 2010 07:43 |
| Last Modified: | 25 Feb 2019 12:17 |
| URI: | http://eprints.iisc.ac.in/id/eprint/31064 |
Actions (login required)
 |
View Item |
