13C Nuclear Magnetic Resonance Studies of the Binding of Alkali and Alkaline Earth Metal Salts to Amides

Rao, Pulla and Balaram, Padmanabhan and Rao, Ramachandra CN (1980) 13C Nuclear Magnetic Resonance Studies of the Binding of Alkali and Alkaline Earth Metal Salts to Amides. In: Journal of the Chemical Society, Faraday Transactions 1, 76 . pp. 1008-1013.

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Abstract

13C resonances of carbonyl and methyl groups in amides are shifted down-field on interaction with alkali and alkaline earth metal salts. The magnitude of the shift depends on the ionic potential of the cation. Ions like ${Li}^+$ bind to the amide carbonyl group both in neat amide solutions as well as in concentrated salt solutions in water.

Item Type:	Journal Article
Publication:	Journal of the Chemical Society, Faraday Transactions 1
Publisher:	Royal Society of Chemistry
Additional Information:	Copyright for this article belongs to the Royal Society of Chemistry.
Department/Centre:	Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Date Deposited:	12 Apr 2005
Last Modified:	19 Sep 2010 04:18
URI:	http://eprints.iisc.ac.in/id/eprint/3058

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