Synthetic Studies Towards the Nor-Triterpene Pfaffic Acid: Synthesis of DEF Ring Fragment Via Tandem Radical Cyclization Rearrangement Reactions

Biju, Purakkattle J and Kaliappan, K and Rao, Subba GSR (2004) Synthetic Studies Towards the Nor-Triterpene Pfaffic Acid: Synthesis of DEF Ring Fragment Via Tandem Radical Cyclization Rearrangement Reactions. In: Arkivoc (Part N). pp. 37-45.

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Abstract

A tandem 5-exo-trig-vinyl-3-exo-radical cyclization-rearrangement reaction and its allylic radical version was developed (8 & 15 to 9 & 16 respectively) for the synthesis of DEF ring system of the nor-tritepene Pfaffic acid 1.

Item Type:	Journal Article
Publication:	Arkivoc
Publisher:	Arkat USA INC
Additional Information:	The copyright for this article belongs to Arkat USA INC.
Keywords:	Synthesis novel tricyclic system;radical cyclisation;nortriterpene
Department/Centre:	Division of Chemical Sciences > Organic Chemistry
Date Deposited:	02 Nov 2007
Last Modified:	19 Sep 2010 04:18
URI:	http://eprints.iisc.ac.in/id/eprint/2890

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